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因燃烧化石燃料而排放的温室气体所导致的环境问题已经成为全球性问题。在这些温室气体中,CO2所占的比例最高。与此同时,CO2在化学工业中有很大的用途。因此,从烟气中分离CO2并将其资源化利用具有十分重要的意义。本文从燃料的前期处理、CO2的分离和捕集、后期封存及其资源化利用三个方面介绍了CO2减排及其资源化利用的途径和方法,并对各减排方法进行了分析和比较,总结了各方法的优劣性及其适用范围,对CO2减排技术的发展前景和面临的挑战进行了展望。
Abstract：The environmental issues due to emissions of greenhouse gases from combustion of fossil fuels have become global problems.Among these greenhouse gases,CO2 makes up the highest proportion in the atmosphere.In addition,CO2 is of great use in chemical industries.So it is crucial to separate CO2 from atmosphere.In this paper,trends and technologies of CO2 emission reduction and resource-oriented utilization were put forward.The technologies were analyzed and compared,and the applicable scope,advantages and disadvantages of the technologies were summarized.The prospects and challenges of CO2 emission reduction technology.
[1]王华,李孔斋,魏永刚,等.二氧化碳减排技术研究[J].科学,2009,61(2):18-22.
[2]张丽香.可再生能源发电的发展现状及前景[J].电力学报,2008,23(1):29-33.
[3]Olajire A A.CO2 capture and separation technologiesfor end-of-pipe applications-A review[J].Energy,2010,35(6):2610-2628.
[4]Herm Z R,Swisher J A,Smit B,et al.Metal organicframeworks as adsorbents for hydrogen purification andprecombustion carbon dioxide capture[J].J Am ChemSoc,2011,133:5664-5667.
[5]Kanniche M,Gros-Bonnivard R,Jauda P,et al.Pre-combustion,post-combustion and oxy-combustion inthermal power plant for CO2 capture[J].AppliedThermal Engineering,2010,30(1):53-62.
[6]夏明珠,严莲荷.二氧化碳的分离回收技术与综合利用[J].现代化工,1999,19(5):46-48.
[7]毛松柏,叶宁,丁雅萍,等.烟道气中CO2回收新技术的开发和应用[J].煤化工,2005,30:25-28.
[8]高健,倪维斗,李政.煤基发电系统燃烧前后氨水吸收CO2的对比[J].热能动力工程,2009,24(1):127-131.
[9]Corti A,Lombardi L.Reduction of carbon dioxide e-missions from a SCGT/CC by ammonia solution ab-sorption preliminary results[J].International Journal ofThermodynamics,2004(4):173-181.
[10]谭大志,张永春,范文杰,等.pH法进行MEA/DEA溶液吸收CO2的研究[J].环境污染与防治,2005(2):1-6.
[11]项菲,施耀,李伟.混合有机胺吸收烟道气CO2的实验研究[J].环境污染与防治,2003,25(4):206-208,225.
[12]陆建刚,郑有飞,陈敏东,等.膜基-氨基酸盐及复合溶液吸收CO2的性能[J].化学工程,2008,36(9):5-8.
[13]Camper D,Bara J E,Gin D L,et al.Room-tempera-ture ionic liquid-amine solution:tunable solvents forefficient and reversible capture of CO2[J].Ind EngChem Res,2008,47(21):8496-8498.
[14]Wappel D,Gronald G,Kalb R,et al.Ionic liquidsfor post-combustion CO2 absorption[J].InternationalJournal of Greenhouse Gas Control,2010(4):486-494.
[15]王轶博,高丽华,滕雯.离子液体中CO2固定过程的研究和应用[J].北京工商大学学报,2008,26(3):17-20.
[16]Hasib-ur-Rahman M,Siaj M,Larachi F.Ionic liq-uids for CO2 capture—Development and progress[J].Chemical Engineering and Processing,2010,49:313-322.
[17]Zhang S,Chen Y,Ren R X F,et al.Solubility of CO2in sulfonate ionic liquids at high pressure[J].J ChemEng Data,2005,50(1):230-233.
[18]Bates E D,Mayton R D,Ntai I,et al.CO2 capture bya task-specific ionic liquid[J].J Am Chem Soc,2002,124:926-927.
[19]王银杰,其鲁,江卫军.高温下硅酸锂吸收CO2的研究[J].无机化学学报,2006,22(2):268-272.
[20]黄煜煜,李振山,蔡宁生.高温CO2吸附/吸收剂的研究进展[J].热能动力工程,2005,20(6):557-561.
[21]何涛,曹彬,胡军印,等.高温下钙基吸附剂吸附CO2的研究[J].化学工程,2007,35(12):8-11.
[22]Li J R,Ma Y G,McCarthy M C,et al.Carbon dioxidecapture-related gas adsorption and separation in met-al-organic frameworks[J].Coordination Chemistry Re-views,2011,255:1791-1823.
[23]Franz J,Scherer J.Impact of ceramic membranes forCO2 separation on IGCC power plant performance[J].Energy Procedia,2011(4):645-652.
[24]Grainger D,Hagg M B.Techno-economic evaluationof a PVAm CO2-selective membrane in an IGCC powerplant with CO2 capture[J].Fuel,2008,87:14-24.
[25]孙正平.工业废气二氧化碳的回收利用[J].中国高新技术企业,2009(13):88-89.
[26]Subramanian K,Asokan K,Jeevarathinam D,et al.Electrochemical membrane reactor for the reduction ofcarbondioxide to formate[J].Applied Electhemistry,2007,37:255-260.
[27]Innocent B,Liaigre D,Pasquier D,et al.Electro-re-duction of carbon dioxide to formate on lead electrodein aqueous medium[J].Applied Electhemistry,2009,39:227-232.
[28]宋爽,裘建平,何志桥,等.CO2一步电化学转化技术的可行性研究[J].航天医学与医学工程,2006,19(3):199-203.
[29]何志桥,裘建平,宋爽,等.Pb-Ag合金电极上KOH甲醇电解液中CO2电化学还原为CO的动力学研究[J].宇航学报,2007,28(6):1774-1778.
[30]Thoms S,Pahlow M,Wolf-Gladrow D A.Model of thecarbon concentrating mechanism in chloroplasts of eu-karyotic algae[J].Theor Biol,2001,208:295-313.
[31]Kurano N,Ikemoto H,Miyashita H H,et a1.Fixationand utilization of carbon dioxide by microalgal photo-synthesis[J].Energy Convers Mgmt,1995,36(6-9):689-692.
[32]Brown L M.Uptake of carbon dioxide from flue gas bymicroalgae[J].Energy Convers Mgmt,1996,37(6-8):1363-1367.
[33]Satoh A,Kurano N,Miyachi S.Inhibition of photo-synthesis by in tracellular carbonic anhydrase in mi-croalgae under excess concentrations of CO2[J].Pho-tosynth Res,2001,68:215-224.
[34]Mandalm R K,Palsson B O.Elemental balancing ofbiomass and medium composition enhances growth ca-pacity in high density Chlorella vulgaris Cultures[J].Biotech Bioeng,1998,59(5):605-611.
[35]左魁昌,左椒兰,胡智泉,等.藻类在环境保护中的作用及其资源化利用研究进展[J].环境污染与防治,2011,33(2):90-98.
[36]马倩倩,孙秀雅,孟波,等.二氧化碳减排技术的研究进展[J].辽宁化工,2009,38(3):176-179.
[37]Figueroa J D,Fout T,Plasynski S,et al.Advances inCO2 capture technology-The U.S.department of ener-gy′s carbon sequestration program[J].Greenhouse GasControl,2008(2):9-20.
[38]栾健,陈德珍.二氧化碳减排技术及趋势[J].能源研究与信息,2009,25(2):88-93.
[39]Aresta M,Dibenedetto A.Utilisation of CO2 as aChemical Feedstock:Opportunities and Challenges[J].Dalton Trans,2007,(28):2975-2992.
[40]张延辉.二氧化碳制化工产品技术研究进展[J].神华科技,2010,8(1):61-67.
[41]Amenomiya Y.Methanol snthesis from CO2+H2Ⅱ[J].Copper-Bed Bary and Trnary Ctalysts Appl Catal,1987,30(1):57-68.
[42]Wambach J,Baiker A,Wokaun A.CO2 Hydrogenationover metal/zirconia catalysts[J].Phys Chem ChemPhys,1999,22(1):5071-5080.
[43]Riduan S N,Zhang Y G,Tackie Y Y.Conversion ofcarbon dioxide into methanol with silanes over N-Het-erocyclic carbene catalysts[J].Angew Chem Int Ed,2009,48(18):3322-3325.
[44]Jessop P G,Ikaryia T,Noyori R.Homogeneous catalyt-ic hydrogenation of supercritical carbon dioxide[J].Nature,1994,368(6468):231-233.
[45]Jessop P G,Ikaryia T,Noyori R.Homogeneous hy-drogenation of carbon dioxide[J].Chemical Review,1995,95(2):259-272.
[46]Munshi P,Heldebrandt D,McKoon E,et al.For-manilide and carbanilde from aniline and carbon diox-ide[J].Tetrahedron Lett,2003,44(13):2725-2726.
[47]Elek J,Nadasdi L,Papp G,et al.Homogeneous hy-drogenation of carbon dioxide and bicarbonate inaqueous solution catalyzed by water-soluble ruthenium(Ⅱ)phosphine complexes[J].Appl Catal A,2003,255(1):59-67.
[48]Barrault J,Forquy C,Menezo J C,et al.Hydroconden-sation of CO2(CO)over supported iron catalysts[J].Catal Lett,1981,17(3-4):373-378.
[49]Lee M D,Lee J F,Chang C S.Hydrogenation of carbondioxide on unpromoted and potassium-promoted ironcatalysts[J].Bull Chen Soc Jpn,1989,62(8):2756-2758.
[50]Ando H,Xu Q,Fujiwara M,et al.Hydrocarbon syn-thesis from CO2 over Fe-Cu catalysts[J].Catal Today,1998,45(1-4):229-234.
[51]Xu L Y,Wang Q X,Liang D B,et al.The Promo-tions of MnO2 and K2O to Fe/Silicalite-2 catalyst forthe production of light alkenes from CO2 hydrogenation[J].Appl Catal A,1998,173(1):19-25.
[52]高健,苗成霞,汪靖伦,等.二氧化碳资源化利用的研究进展[J].石油化工,2010,5(39):465-475.
[53]Lin S Y,Harada M,Suzuki Y,et al.Hydrogen pro-duction from coal by separating carbon dioxide duringgasification[J].Fuel,2002,81:2079-2085.
[54]Lin S Y,Harada M,Suzuki Y,et al.Comparison ofpyrolysis products between coal,Coal/CaO,andCoal/Ca(OH)2 Materials[J].Energy Fuels,2003,17(3):602-607.
基本信息:
DOI：
中图分类号:X701
引用信息:
[1]米铁,黄震,余新明.CO_2减排技术研究进展[J].江汉大学学报(自然科学版),2012,40(01):50-56.
基金信息:
湖北省自然科学基金重点项目(2009ACDA11)