nav emailalert searchbtn searchbox tablepage yinyongbenwen piczone journalimg journalInfo searchdiv qikanlogo popupnotification

请选择需要下载的pdf数据

正在翻译英文数据 ...
paper paperNew
2015, 03, v.43 197-203
聚合物微胶囊的形态结构和性能表征方法
基金项目(Foundation): 湖北省教育厅科学技术研究项目(B2013162); 武汉市科技局晨光计划资助项目(2013071004010473); 光电化学材料与器件省部共建教育部重点实验室开放课题(JDGD-2012-17)
邮箱(Email):
DOI: 10.16389/j.cnki.cn42-1737/n.2015.03.001
摘要:

聚合物微胶囊作为一类新型功能高分子材料,在化学、材料科学、生物医学等诸多领域具有广阔的应用前景。聚合物微胶囊的形态结构、粒径大小及分布、芯材含量和机械强度等性能是决定其应用成功与否的关键。综述了聚合物微胶囊的形态结构和性能表征的几种经典和现代的仪器方法,详细阐述了各种表征方法的特点及用途,并对其优势和不足进行了比较。

Abstract:

Polymer microcapsules are a kind of new functional polymer materials which are widely appliedin the fields of chemistry,material science and biomedical science,etc. The surface morphology,diame-ter distribution,core content and mechanical strength of the polymer microcapsules are the key fac-tors of the success of application of polymer microcapsules. The characterization of morphological structureand properties of polymer microcapsules with classical and modern instrumental methods has been re-viewed. The characteristic and application of these methods have also been pointed out. The advantagesand limitations of all methods are compared.

参考文献

[1]BENITA S.Microencapsulation:methods and industrial applications[M].London:Informa Healthc,2005.

[2]郭生伟,赵越.聚合物微胶囊的研究进展[J].高分子材料科学与工程,2010,26(12):152-155.

[3]许时婴,张晓鸣,夏书芹,等.微胶囊技术:原理与应用[M].北京:化学工业出版社,2006.

[4]WAGDARE N A,MARCELIS A T M,BOOM R M,et al.Porous microcapsule formation with microsieve emulsification[J].Journal of Colloid and Interface Science,2011,355(2):453-457.

[5]FAN C J,ZHOU X D.Influence of operating conditions on the surface morphology of microcapsules prepared by in situ polymerization[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2010,363(1/2/3):49-55.

[6]汪海平,胡思前,张远方.溶剂挥发法制备苯乙烯微胶囊[J].化工新型材料,2012,40(3):52-53.

[7]FAN D W,DENG Y M,HAO J C.In situ fabrication and electrochemical behavior of amino acid polyoxometalate nanoparticlesembedded microcapsules[J].Amino Acids,2010,39:1363-1367.

[8]宋健,陈磊,李效军.微胶囊化技术及应用[M].北京:化学工业出版社,2001.

[9]唐欣欣.环氧树脂阴离子催化剂型固化剂微胶囊的制备及性能表征[D].哈尔滨:哈尔滨工业大学,2011.

[10]CARUSO M M,BLAISZIK B J,JIN H,et al.Robust,double-walled microcapsules for self-healing polymeric materials[J].ACS Applied Materials&Interfaces,2010,2(4):1195-1199.

[11]WANG X L,SHI J F,JIANG Z Y,et al.Preparation of ultrathin,robust protein microcapsules through template-mediated interfacial reaction between amine and catechol groups[J].Biomacromolecules,2013,14(11):3861-3869.

[12]宋正红,张志英,董知之,等.用差示扫描量热法求微胶囊的壁材厚度[J].天津工业大学学报,2006,25(3):5-7.

[13]孙多先,陈益清,杨军,等.APA微胶囊膜厚的理论计算与实验研究[J].生物医学工程学杂志,2002,19(4):645-647.

[14]LIAO L P,ZHANG W,ZHAO Y,et al.Preparation and characterization of microcapsules for self-healing materials[J].Chemical Research in Chinese Universities,2010,26(3):496-500.

[15]ZHU D Y,RONG M Z,ZHANG M Q.Preparation and characterization of multilayered microcapsule-like microreactor for selfhealing polymers[J].Polymer,2013,54(16):4227-4236.

[16]YUAN L,CHEN F,GU A J,et al.Synthesis of poly(urea-formaldehyde)encapsulated dibutyltin dilaurate through the self-catalysis of core materials[J].Polymer Bulletin,2014,71(1):261-273.

[17]时雨荃,杜春霞,赵镇南,等.相变微胶囊壁材结构与力学强度及密封性的关系[J].高分子材料科学与工程,2005,21(5):188-191.

[18]CHEN W L,FU X W,GE W B,et al.Microencapsulation of bisneopentyl glycol dithiopyrophosphate and its flame retardant effect on polyvinyl alcohol[J].Polymer Degradation and Stability,2014,102:81-87.

[19]LI H Y,WANG R G,HU H L,et al.Surface modification of self-healing poly(urea-formaldehyde)microcapsules using silanecoupling agent[J].Applied Surface Science,2008,255(5):1894-1900.

[20]王广金,周明宇,褚良银,等.制备具有通孔膜结构的聚醚砜微囊[J].四川大学学报:工程科学版,2005,37(5):55-61.

[21]WANG H P,YUAN Y C,RONG M Z,et al.Microencapsulation of styrene with melamine-formaldehyde resin[J].Colloid and Polymer Science,2009,287(9):1089-1097.

[22]陈建峰,陈峰,谢吉民,等.微胶囊化聚磷酸铵阻燃环氧树脂的研究[J].涂料工业,2010,40(11):15-18.

[23]NGUYEN M,ARIPIN N F K,CHEN X G,et al.Methodologies used for the characterization of nano-and microcapsules[M].New York:John Wiley&Sons Ltd,2014:65-94.

[24]DRUSCH S,BERG S.Extractable oil in microcapsules prepared by spray-drying:localisation,determination and impact on oxidative stability[J].Food Chemistry,2008,109(1):17-24.

[25]ALAY S,ALKAN C,GDE F.Synthesis and characterization of poly(methyl methacrylate)/n-hexadecane microcapsules using different cross-linkers and their application to some fabrics[J].Thermochimica Acta,2011,518(1/2):1-8.

[26]PESSI J,SANTOS H A,MIROSHNYK I,et al.Microfluidics-assisted engineering of polymeric microcapsules with high encapsulation efficiency for protein drug delivery[J].International Journal of Pharmaceutics,2014,472(1/2):82-87.

[27]YANG Z M,PENG Z,LI J H,et al.Development and evaluation of novel flavour microcapsules containing vanilla oil using complex coacervation approach[J].Food Chemistry,2014,145:272-277.

[28]ZHAO Y,ZHANG W,LIAO L P,et al.Self-healing coatings containing microcapsule[J].Applied Surface Science,2012,258(6):1915-1918.

[29]郑振荣,马晓光,张晓丹.海藻酸钠-壳聚糖相变储热微胶囊的制备[J].纺织学报,2014,35(2):18-22.

[30]FEREIDOON A,GHORBANZADEH A M,JAHANSHAHI M.Effect of nanoparticles on the morphology and thermal properties of self-healing poly(urea-formaldehyde)microcapsules[J].Journal of Polymer Research,2013,20(6):151.

[31]YANG J L,KELLER M W,MOORE J S,et al.Microencapsulation of isocyanates for self-healing polymers[J].Macromolecules,2008,41(24):9650-9655.

[32]蓝洪桥,洪玮,花丹,等.气相色谱法测定薄荷醇微胶囊的包裹率[J].香料香精化妆品,2011(1):6-8.

[33]ESSER-KAHN A P,SOTTOS N R,WHITE S R,et al.Programmable microcapsules from self-immolative polymers[J].Journal of the American Chemical Society,2010,132(30):10266-10268.

[34]DISPINAR T,COLARD C A L,DU PREZ F E.Polyurea microcapsules with a photocleavable shell:UV-triggered release[J].Polymer Chemistry,2013,4:763-772.

[35]龙吉云.高含量天然维生素E油微胶囊化研究[D].南昌:南昌大学,2011.

[36]杨君,赵生,陈科兵,等.薄荷香精微胶囊包埋率不同测定方法比较分析[J].食品科学,2010,31(5):239-242.

[37]FERY A,DUBREUIL F,MHWALD H.Mechanics of artificial microcapsules[J].New Journal of Physics,2004,6(1):18.

[38]汪海平,容敏智,章明秋.微胶囊填充型自修复聚合物及其复合材料[J].化学进展,2010,22(12):2397-2407.

[39]方一,李路海,胡朝丽,等.微胶囊机械性能表征方法的研究[J].北京印刷学院学报,2008,16(6):34-37.

[40]侯丹丹,李会静,宋慧一,等.非水相体系中海藻酸钠-壳聚糖微胶囊粒径及强度性能[J].化工学报,2012,63(5):1522-1528.

[41]GAO C Y,LEPORATTI S,MOYA S,et al.Stability and mechanical properties of polyelectrolyte capsules obtained by stepwise assembly of poly(styrenesulfonate sodium salt)and poly(diallyldimethyl ammonium)chloride onto melamine resin particles[J].Langmuir,2001,17(11):3491-3495.

[42]GAO C Y,DONATH E,MOYA S,et al.Elasticity of hollow polyelectrolyte capsules prepared by the layer-by-layer technique[J].European Physical Journal E,2001,5(1):21-27.

[43]VINOGRADOVA O I,LEBEDEVA O V,KIM B.Mechanical behavior and characterization of microcapsules[J].Annual Review of Materials Research,2006,36(1):143-178.

[44]LEE J,ZHANG M,BHATTACHARYYA D,et al.Micromechanical behavior of self-healing epoxy and hardener-loaded microcapsules by nanoindentation[J].Materials Letters,2012,76:62-65.

[45]赵钊,计宏伟,陈金龙,等.自修复体系中微胶囊壁材力学性能的测试与表征[J].实验力学,2013,28(5):580-585.

[46]GHORBANZADEH A M,FEREIDOON A,JAHANSHAHI M,et al.Effect of nanoparticles on the micromechanical and surface properties of poly(urea-formaldehyde)composite microcapsules[J].Composites Part B Engineering,2014,56:450-455.

[47]赵德.脲醛树脂制备毒死蜱微胶囊及性能表征[D].泰安:山东农业大学,2006.

[48]HIGUCHI T.Mechanism of sustained-action medication:theoretical analysis of rate of release of solid drugs dispersed in solid matrices[J].Journal of Pharmaceutical Sciences,1963,52(12):1145-1149.

[49]KORSMEYER R W,GURNY R,DOELKER E,et al.Mechanisms of solute release from porous hydrophilic polymers[J].International Journal of Pharmaceutics,1983,15(1):25-35.

[50]APPARAO B,SHIVALINGAM M R,REDDY K Y V,et al.Design and evaluation of sustained release microcapsules containing diclofenac sodium[J].International Journal of Pharmaceutical and Biomedical Research,2010,1(3):90-93.

[51]HEDAOO R K,MAHULIKAR P P,GITE V V.Synthesis and characterization of resorcinol-based cross linked phenol formaldehyde microcapsules for encapsulation of pendimethalin[J].Polymer-Plastics Technology and Engineering,2013,52(3):243-249.

[52]PEA B,PANISELLO C,ARESTéG,et al.Preparation and characterization of polysulfone microcapsules for perfume release[J].Chemical Engineering Journal,2012,179:394-403.

[53]潘勇军,薛寒兵,张飞,等.茉莉香精微胶囊的制备和表征[J].染整技术,2009,31(11):33-37.

[54]王奎涛,葛艳蕊,冯薇,等.玫瑰香精微胶囊缓释性的影响因素研究[J].日用化学工业,2005,35(6):368-370.

[55]张兴祥,王馨,吴文健.相变材料胶囊制备与应用[M].北京:化学工业出版社,2009.

[56]杨保平,席满意,崔锦峰,等.乙二醇改性聚脲微胶囊相变材料的研制[J].应用化工,2014,43(1):118-120.

[57]李庆丹,朱冬梅,李娇娇,等.石蜡相变微胶囊的制备及相变性能研究[J].精细化工,2011,28(1):10-13.

基本信息:

DOI:10.16389/j.cnki.cn42-1737/n.2015.03.001

中图分类号:O631.1

引用信息:

[1]李猛强,汪海平.聚合物微胶囊的形态结构和性能表征方法[J].江汉大学学报(自然科学版),2015,43(03):197-203.DOI:10.16389/j.cnki.cn42-1737/n.2015.03.001.

基金信息:

湖北省教育厅科学技术研究项目(B2013162); 武汉市科技局晨光计划资助项目(2013071004010473); 光电化学材料与器件省部共建教育部重点实验室开放课题(JDGD-2012-17)

引用

GB/T 7714-2015 格式引文
MLA格式引文
APA格式引文