| 469 | 13 | 22 |
| 下载次数 | 被引频次 | 阅读次数 |
超重力旋转床是一种强化化学工业过程的新型反应器,利用高速旋转填料所产生的离心力来模拟超重力环境,液体在高分散、高湍动、强混合以及界面的快速更新下与气相以极大的相对速度在填料的弯曲孔道中进行逆向接触,极大地强化了气液传质过程而不液泛。对影响超重力旋转床气液传质效果的因素,如填料、转子转速以及气/液体流量等进行了综述,并在此基础上,介绍了典型的气液传质理论和近年来国内外对超重力旋转床中气液传质理论及气液传质模型的研究进展,最后对超重力旋转床气液传质的强化技术进行了展望。
Abstract:Rotating packed bed is a kind of new reaction device in industrial chemistry process,used thecentrifugal force generated by materials filling in high speed rotating to imitate the hypergravity enviro-ment,the liquid contacted reversely with the gas phase at high relative velocity in curving hole of packingbed under the conditions of high dispersion,high turbulence,strong mixture and quick renew of inter-face,it strongly intensified the gas-liquid mass transference. Reviewed the influence factors on the effectof gas-liquid mass transference in hypergravity rotating packed bed,introduced the typical theory on gas-liquid mass transference,moreover,introduced recent progress of the theory and the model of gas-liquidtransference in hypergravity rotating packed bed,prospected the intensifying technology in this field.
[1]陈建峰.超重力技术及应用[M].北京:化学工业出版社,2002.
[2]BUCKLIN R W,WON K W.Higee contactors for selective H2S removal and superdehydration[C]//SMITH D S.Preceeding of the Laurance Reid Gas Conditioning Conference.Portland:University of Oklahoma,1997.
[3]LIU S,LIN C,WU S,et al.Characteristics of a rotating packed bed[J].Industrial Engineering Chemistry Research,1996,35:3590-3596.
[4]刘有智.超重力化工过程与技术[M].北京:国防工业出版社,2008.
[5]CHEN S,LIN Y,LIN C,et al.Packing characteristics for mass transfer in a rotating packed bed[J].Industrial Engineering Chemistry Research,2006,45:6846-6853.
[6]杨玲,张鹏远.旋转床内填料表面传质特性的研究[J].北京化工大学学报,2001,28(3):13-16.
[7]吴杰,吴菲,石红,等.超重力旋转床转子填料形状对传质系数的影响[J].江汉大学学报:自然科学版,2014,42(2):24-26.
[8]CHEN S,LIU S.Absorption of VOCs in a rotating packed bed[J].Industrial Engineering Chemistry Research,2002,41:1583-1588.
[9]QIAN Z,XU L B,CAO H B.Modeling study on absorption of CO2by aqueous solutions of N-Methyldiethanolamine in rotating packed bed[J].Industrial Engineering Chemistry Research,2009,48:9261-9267.
[10]SUN B C,ZOU H K,CHU G W.Determination of mass-transfer coefficient of CO2in NH3and CO2absorption by materials balance in a rotating packed bed[J].Industrial Engineering Chemistry Research,2012,51:10949-10954.
[11]CHANG C Y,CHEN Y S,LIANG M S,et al.Absorption of ethanol into water and glycerol/water solution in a rotating packed bed[J].Taiwan Institution Chemical Engineers,2009,40:418.
[12]TAN C S,LEE P L.Supercritical CO2desorption of activated carbon loaded with 2,2,3,3-Tetrafluoro-1-Propanol in a rotating packed bed[J].Environmental Science Technology,2008,42:2150.
[13]潘朝群,张亚君,邓先和,等.多级雾化超重力旋转床中气液传质实验研究[J].华南理工大学学报,2006,34(3):67-71.
[14]竺洁松,郭锴,冯元鼎,等.旋转床填料中的传质及其模型化[J].高校化学工程学报,1998,12(3):219-225.
[15]曹会博,李振虎,郝国均,等.超重力络合铁法脱除石油伴生气中H2S的中试研究[J].石油化工,2009,38(9):971-973.
[16]孙志斌.超重力氨法烟气脱硫技术基础研究[D].太原:中北大学,2013.
[17]GUO F,ZHENG C,GUO K,et al.Hydrodynamics and mass transfer in cross-flow rotating packed bed[J].Chemical Engineering Science,1997,52:3853-3859.
[18]CHEN S,CHUN H,LIN C,et al.Volatile organic compounds absorption in a cross-flow rotating packed bed[J].Environmental Science Technology,2008,42:2631-2636.
[19]SUN B C,WANG X M,CHEN J M.Simultaneous absorption of CO2and NH3into water in a rotating packed bed[J].Industrial Engineering Chemistry Research,2009,48:11175-11180.
[20]ZHANG L L,WANG J X,XIANG Y.Absorption of carbon dioxide with ionic liquid in a rotating packed bed contactor:mass transfer study[J].Industrial Engineering Chemistry Research,2011,50:6957-6964.
[21]杨旷.超重力旋转床微观混合与气液传质特性研究[D].北京:北京化工大学,2010.
[22]许明,张建文,陈键锋,等.超重力旋转床中水脱氧过程的模型化研究[J].高校化学工程学报,2005,19(3):309-314.
[23]王贺,刘有智.超重力法臭氧处理三硝基甲苯碱性废水传质模型[J].化学工程,2008,36(12):6-9.
[24]钱智,徐联斌.旋转填充床中伴有可逆反应的气液传质[J].化工学报,2010,61(4):832-837.
基本信息:
DOI:10.16389/j.cnki.cn42-1737/n.2015.02.015
中图分类号:TQ021.4
引用信息:
[1]方健,詹丽,余国贤,等.超重力旋转床中气液传质性能的研究进展[J].江汉大学学报(自然科学版),2015,43(02):182-187.DOI:10.16389/j.cnki.cn42-1737/n.2015.02.015.
基金信息:
江汉大学高层次人才科研基金项目(2010018)
2015-04-28
2015-04-28